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Cheng, Chien-Hong

Title： Professor                                             Chinese Version

Education：

University of Rochester(USA)(Ph.D.) (1978)
National Tsing Hua University(B.S.) (1971)
Office： Chemistry Building R608
Phone number： +886-3-5721454    Fax：+886-3-5711082
E-mail： chcheng@mx.nthu.edu.tw
Web site： http://mx.nthu.edu.tw/~chcheng

Professional Experience：

2011 ~ 2012
2010 ~ 2014
2010 ~ 2010
2009 ~ 2010
2006 ~ 2009
2002 ~ 2006
1990 ~ 1993
1984 ~ 1985
1984 ~
1979 ~ 1984
1978 ~ 1979
President, Chemical Society Located in Taipei
Vice President of Academic Affairs of NTHU
Dean of Research and Development of NTHU
President-Elect, Chemical Society Located in Taipei
Director General, Department of Natural Sciences, National Science Council
Director, Optoelectronic Center of NTHU
Chairman, Department of Chemistry of  NTHU
Visiting Scientist, Department of Chemistry, Princeton University
Professor of NTHU
Associate Professor of NTHU
Postdoctoral Research, University of Rochester

Awards and Honors：

2014
2013
2009 ~ 2012
2009
2004 ~ 2007
2003
2002
2001
1995 ~ 2001
1993
1991 ~ 1995
1988 ~ 1990

TECO Award
Professor Chau-Ting Chang Memorial Lectureship
National Chair Professor, Ministry of Education
Fellow of Royal Society of Chemistry
National Chair Professor, Ministry of Education
Chair Professor, National Tsing Hua University
Ministry of Education Science Award
Chinese Chemical Society (Taiwan) Award
Fellow of National Science Council
Chinese Culture and Academic Foundation Award
Outstanding Research Award of National Science Council
Outstanding Research Award of National Science Council

Research Interest：

(I). Transition metal-catalyzed carbon-carbon bond formation.
(II). Synthesis of new organic and organometallic electroluminescent materials and fabrication  
      of electroluminescent devices.


Publications：(After 2010)
  1. Korivi, R. P.; Wu Y. -C.; Cheng C. -H.* Protecting-Group-Free Total Synthesis of Isoquinoline Alkaloids by Nickel-Catalyzed Annulation of o-Halobenzaldimine with an Alkyne as the Key Step. Chem. Eur. J. 2010, 16, 282-287.
  2. Chou, H. -H.; Shih, H. -H.; Cheng, C. -H.* Triptycene Derivatives as High-TgHost Materials for Various Electrophosphorescent Devices. J. Mater. Chem.2010,20, 798-805.
  3. Mannathan, S.; Cheng, C.-H.*Cobalt-Catalyzed Regio- and Stereoselective Intermolecular Enyne Coupling: an Efficient Route to 1,3-Diene Derivatives. Chem. Commun.2010, 46, 1923-1925.
  4. Bhuvaneswari, S.; Jeganmohan, M.; Cheng, C.-H.*Platinum-Catalyzed Multi-Step Reaction of Propargyl Alcohols with N-Heteroaromatics.Chem. Asian J.2010, 5, 141-146.
  5. Jeganmohan, M.; Bhuvaneswari, S.; Cheng, C.-H.*Synthesis of N-Arylated 1,2-Dihydroheteroaromatics Through the Three-Component Reaction of Arynes with N-Heteroaromatics and Terminal Alkynes or Ketones. Chem. Asian J.2010, 5, 153-159.
  6. Wong Y. -C.; Parthasarathy, K.; Cheng, C. -H.*Direct Synthesis of Aryl Ketones by Nickel-Catalyzed Addition of Arylboronic Acids to Nitriles.Org. Lett.2010,12, 1736-1739.
  7. Thirunavukkarasu V. S.;Parthasarathy, K.; Cheng, C. -H.*One‑Pot Synthesis of Diarylmethylidenefluorenes and Phenanthrenes by Palladium-Catalyzed Multiple C−H Bond Functionalization.Chem. Eur. J. 2010, 16,1436-1440.
  8. Gandeepan, P.; Parthasarathy, K.; Cheng, C. -H.*Synthesis of Phenanthrone Derivatives from sec-Alkyl Aryl Ketones and Arylhalides via a Palladium Catalyzed Dual C−H Bond Activation and Enolate CyclizationJ. Am. Chem. Soc.2010, 132, 8569-8571.
  9. Liu, C. -C.; Parthasarathy, K.; Cheng, C. -H.* Synthesis of Highly Substituted Isoquinolone Derivatives by Nickel-Catalyzed Annulation of 2-Halobenzamides with Alkynes.Org. Lett. 2010,12, 3518-3521.
  10. Karthikeyan, J.; Jeganmohan, M.; Cheng, C. -H.*Cobalt-Catalyzed Addition Reaction of Organoboronic Acids with Aldehydes: Highly Enantioselective Synthesis of Diarylmethanols.Chem. Eur. J. 2010, 16,8989-8992.
  11. Yang, C. -M.; Jeganmohan, M.; Parthasarathy, K.; Cheng, C. -H.* Nickel Catalyzed Three-Component Coupling of Alkynes with Enones and Alkenyl Boronic Acids: A Novel Route to Substituted 1,3-Dienes.Org. Lett. 2010,12, 3610-3613.
  12. Chou, H. -H.; Cheng, C. -H.* A Highly Efficient Universal Bipolar Host for Blue, Green, and Red Phosphorescent OLEDs. Adv. Mater.2010, 22, 2468-2471.
  13. Zhang, G. H.; Chou, H. -H.; Jiang, X. Q.; Sun, P. P.*; Cheng, C. -H.*; Ooyama, Y.; Harima.Y.Highly Efficient Organic Light-Emitting Diodes (OLEDs) Based on An Iridium Complex with Rigid Cyclometalated Ligand. Org. Electron.2010, 11, 632-640.
  14. Wu, S. -H.; Ling, J. -W.; Lai, S. -H.; Huang, M. -J.; Cheng, C. -H.; Chen, I. -C.* Dynamics of the Excited States of [Ir(ppy)2bpy]+ with Triple Phosphorescence. J. Phys. Chem. A2010, 114, 10339-10344.
  15. Zhang, G. H.; Wu, F. -I.; Jiang, X. Q.; Sun, P. P.*; Cheng, C. -H.* Iridium(III) Complexes with Cyclometalated Styrylbenzoimidazole Ligands: Synthesis, Electrochemistry and as Highly Efficient Emitters for Organic Light-Emitting Diodes. Synth. Met.2010, 160, 1906-1911.
  16. Zhang, G. H.; Chou, H. -H.; Jiang, X. Q.; Sun, P. P.*; Cheng, C. H.* Highly Efficient White Organic Light-Emitting Diodes Based on Broad Excimer Emission of Iridium Complex. Org. Electron.2010, 11, 1165-1171.
  17. Lai, S. -H., Ling, J. -W., Huang, Y. -M., Huang, M. -J., Cheng, C. -H., Chen, I. -C.*. Characterization of Ir(ppy)3 and [Ir(ppy)2bpy]+ by Infrared, Raman Spectra and Surface-Enhanced Raman Scattering. J. Raman Spectrosc.2011, 42, 332-338.
  18. Chen, H.; Huang, Z. -B.; Hu, X. -M.; Tang, G.; Xu, P. -X.; Zhao, Y. -F.*; Cheng, C. -H.* Nickel-Catalyzed Cross-Coupling of Aryl Phosphates with Arylboronic Acids. J. Org. Chem.2011, 76, 2338-2344.
  19. Yang, X. -H.; Wu, F. -I.; Haverinen, H.; Li, J. -A.; Cheng, C. -H.; Jabbour, G. -E.* Efficient Organic Light-Emitting Devices with Platinum-Complex Emissive Layer. Appl. Phys. Lett.2011, 98, 033302/1-033302/3.
  20. Muralirajan, K.; Parthasarathy, K.; Cheng, C. -H.*Regioselective Synthesis of Indenols via Rhodium Catalyzed C−H Activation and Carbocyclization of Aryl Ketones and Alkynes. Angew. Chem. 2011,123, 4255-4258; Angew. Chem. Int. Ed.2011,50, 4169-4172.
  21. Wei, C. -H.; Mannathan, S.; Cheng, C. -H.*Enantioselective Synthesis of β-Substituted Cyclic Ketones via Cobalt Catalyzed Asymmetric Reductive Coupling of Alkynes With Alkenes. J. Am. Chem. Soc.2011,133, 6942-6944.
  22. Fan, C. -C.; Sun, P. -P.; Su, T. -H.; Cheng, C. -H.*Host and Dopant Materials for Idealized Deep Red Organic Electrophosphorescence Devices. Adv. Mater.2011,23, 2981-2985.
  23. Lin, S. -H.; Wu, F. -I.*; Tsai, H. -Y.; Chou, P. -Y.; Chou, H. -H.; Cheng, C. -H.*; Liu, R. -S.* Highly Efficient Deep-Blue Organic Electroluminescent Devices Doped with Hexaphenylanthracene Fluorophores. J. Mater. Chem. 2011, 21, 8122-8128.
  24. Hsieh, C. -H.; Wu, F. -I.; Fan, C. -H.; Huang, M. -J.; Lu, K. -Y.; Chou, P. -Y.; Ou-Yang, Y. H.; Wu, S. -H.; Chen, I. -C.; Chou, S. -H.; Wong, K. -T.; Cheng, C. -H.*Design and Synthesis of Iridium Bis(carbene) Complexes for Efficient Blue Electrophosphorescence.Chem. Eur. J.2011, 17, 9180-9187.
  25. Chen, Y. -H.; Chou, H. -H.; Su, T. -H.; Chou, P. -Y.; Wu, F. -I.; Cheng, C. -H.* Synthesis and Photo- and Electroluminescence Properties of 3,6-Disubstituted Phenanthrenes: an Alternative of Blue Host Material. Chem. Commun.2011, 47, 8865-8867.
  26. Chen, C. -H.; Wu, F. -I.*; Tsai, Y. -Y.; Cheng, C. -H*. Platinum Phosphors Containing an Aryl-Modified β-Diketonate: Unusual Effect of Molecular Packing on Photo- and Electroluminescence. Adv. Funct. Mater.2011,21, 3150-3158.
  27. Karthikeyan, J.;Parthasarathy, K.; Cheng, C.-H.* Synthesis of Biarylketones and Phthalides from Organoboronic Acids and Aldehydes Catalyzed by Cobalt Complexes. Chem. Commun.2011, 47, 10461-10463.
  28. Tang, G.*; Cheng, C. -H.* Synthesis of α-Hydroxy Carboxylic Acids via a Nickel(II)-Catalyzed Hydrogen Transfer Process. Adv. Synth. Catal.2011, 353, 1918-1922.
  29. Tsai, H. -R.; Lu, K. -Y.; Lai, S. -H.; Fan, C. -H.; Cheng, C. -H.*; Cheng, I. -C.* Metal-Ligand Bonding Strength of Fluoro-Substituted Cyclometalated Iridium(III) Complexes from Raman. J. Phys. Chem. C2011, 115, 17163-17174.
  30. Karthikeyan, J.;Cheng, C. -H.* Synthesis of Phenanthridinones from N-Methoxybenzamides and Arenes by Multiple Palladium-Catalyzed C−H Activation Steps at RoomTemperature. Angew. Chem. 2011, 123, 10054-10057; Angew. Chem. Int. Ed.2011, 50, 9880-9883.
  31. Lu, K. -Y.; Chou,H. -H.; Hsieh,C. -H.; Tsai,H. -R.; Chen, I. -C.*;Cheng, C. -H.*Wide-Range Color Tuning of Iridium Biscarbene Complexes from Blue to Red by Different N^N Ligands: an Alternative Route for Adjusting the Emission Colors. Adv. Mater.2011,23, 4933-4937.
  32. Thirunavukkarasu V. S.; Cheng, C. -H.* Pd-Catalyzed Multiple C−H Functionalization to Construct Biologically Active Compounds from Aryl Aldoxime Ethers with Arenes. Chem. Eur. J.2011, 17, 14723-14726.
  33. Gandeepan, P.; Cheng, C. -H.* Allylic Carbon-Carbon Double Bond Directed Pd-Catalyzed Oxidative ortho-Olefination of Arenes. J. Am. Chem. Soc.2012,134, 5738-5741.
  34. Jayakumar, J.;Parthasarathy, K.; Cheng, C. -H.* One-Pot Synthesis of Isoquinolinium Salts by Rhodium Catalyzed C−H Bond Activation: Application to the Total Synthesis of Oxychelerythrine. Angew. Chem.2012,124, 201-204; Angew. Chem. Int. Ed.2012,51, 197-200.
  35. Shih, W. -C.; Teng, C. -C.; Parthasarathy, K.; Cheng, C. -H.* Nickel-Catalyzed Cyclization of ortho-Iodoketoximes and ortho-Iodoketimines with Alkynes: Synthesis of Highly Substituted Isoquinolines and Isoquinolinium Salts. Chem. Asian J.2012, 7, 306-313.
  36. Gandeepan, P.; Parthasarathy, K.; Su, T. -H.; Cheng, C. -H.* Iron-Catalyzed Synthesis of β-Chlorovinyl and α,β-Alkynyl Ketones from Terminal and Silyl Alkynes with Acid Chlorides. Adv. Synth. Catal.2012,354, 457-468.
  37. Parthasarathy, K.; Han, H.; Prakash, C.; Cheng, C. -H.* Synthesis of Isochromenones and Oxepines via Pd Catalyzed Cascade Cyclization of Alkynes and Arynes Involving a C−H Activation. Chem. Commun.2012, 48, 6580-6582.
  38. Mannathan, S.; Cheng, C. -H.* Synthesis of trans-Disubstituted Alkenes by Cobalt Catalyzed Reductive Coupling of Terminal Alkynes with Activated Alkenes. Chem. Eur. J.2012, 11771-11777.
  39. Wu,C. -A.; Chou, H. -H.; Shih, C. -H.; Wu, F. -I.; Cheng, C. -H.*; Huang, H. -L.; Chao, T. -C.; Tseng, M. -R. Synthesis and Physical Properties of meta-Terphenyloxadiazole Derivatives and the Application as Electron Transporting Materials for Blue Phosphorescent and Fluorescent Devices. J. Mater. Chem. 2012, 22, 17792-17799.
  40. Parthasarathy, K.; Senthilkumar, N.; Jayakumar, J.; Cheng, C. -H.* Ru(II) Catalyzed C−H Bond Activation for the Synthesis of Substituted Isoquinolinium Salts from Benzaldehydes, Amines and Alkynes. Org. Lett.2012,14, 3478-3481.
  41. Muralirajan, K.; Parthasarathy, K.; Cheng, C. -H.* Ru(II)-Catalyzed Amidation of 2-Arylpyridines with Isocyanates via C−H Activation. Org. Lett.2012,14, 4262-4265.
  42. Gandeepan, P.; Hung, C. -H.; Cheng, C. -H.* Pd-Catalyzed Double C−H Bond Activations of Diaryl Ketones for the Synthesis of Fluorenones. Chem. Commun.2012,48, 9379-9381.
  43. Wei, C. -H.; Mannathan, S.; Cheng, C. -H.* Regio- and Enantioselective Cobalt-Catalyzed Reductive [3+2] Cycloaddition Reaction of Alkynes with Cyclic Enones: A Novel Route to Bicyclic Tertiary Alcohols. Angew. Chem. 2012,124, 10744-10747; Angew. Chem. Int. Ed.2012,51, 10592-10595.
  44. Chou, H. -H.; Chen, Y. -H.; Hsu, H. -P.; Chang, W. -H.; Chen, Y. -H.; Cheng, C. -H.* Synthesis of Diimidazolylstilbenes as n-Type Blue Fluorophores; Alternative Dopant Materials for Highly Efficient Electroluminescent Devices. Adv. Mater.2012,24, 5867-5871.
  45. Chen, M. -H.; Mannathan, S.; Lin, P. -S.; Cheng, C. -H.* Cobalt(II)-Catalyzed 1,4-Addition of Organoboronic Acids to Activated Alkenes: An Application to Highly cis-Stereoselective Synthesis of Aminoindane Carboxylic Acid Derivatives. Chem. Eur. J.2012,18, 14918-14922.
  46. Karthikeyan, J.;Haridharan, R.; Cheng, C -H.* Rhodium(III)-Catalyzed Oxidative C−H Coupling of N-Methoxybenzamides with Arylboronic Acids: One-Pot Synthesis of Phenanthridinones under Mild Conditions. Angew. Chem. 2012,124, 12509-12513; Angew. Chem. Int. Ed.2012,51, 12343-12347.
  47. Huang, P. -C.; Parthasarathy, K.; Cheng, C. -H.* Copper-Catalyzed Intramolecular Oxidative C−H Functionalization and C−N Formation of 2-Aminobenzophenones: Unusual Pseudo 1,2-Shift of the Substituent on the Aryl Ring. Chem. Eur. J.2013, 19, 460-464.
  48. Liao, C. -Y.; Chen, C. -P.; Chang, C. -C.; Hwang, G. -W.; Chou, H. -H.*; Cheng, C. -H.* Synthesis of Conjugated Polymers Bearing Indacenodithiophene and Cyclometalated Platinum(II) Units and their Application inOrganic Photovoltaics. Sol. Energ. Mat. Sol.C2013, 109, 111-119.
  49. Mannathan, S.; Cheng, C. -H.* Nickel-Catalyzed Regio- and Diastereoselective Intermolecular Three-Component Coupling of Oxabicyclic Alkenes with Alkynes and Organoboronic Acids. Chem. Commun.2013, 49, 1557-1559.
  50. Muralirajan, K.; Cheng, C. -H.* Rh(III)-Catalyzed Synthesis of Cinnolinium Salts from Azobenzenes and Alkynes: Application to the Synthesis of Indoles, and Cinnolines. Chem. Eur. J.2013, 19, 6198-6202.
  51. Yeh, C. -H.; Korivi, Rajendra; Cheng, C. -H.* Ene-Carbonyl Reductive Coupling Mediated by Zinc and Ammonia for the Synthesis of γ-Hydroxybutyric Acid Derivatives. Adv. Synth. Catal.2013, 355, 1338-1344.
  52. Gandeepan, P.; Cheng, C. -H.* Pd-Catalyzed π-Chelation Assisted ortho-C−H Activation and Annulation of Allylarenes with Internal Alkynes. Org. Lett.2013,15, 2084-2087.
  53. Senthilkumar N.; Parthasarathy K.; Gandeepan, P.; Cheng, C. -H.* Synthesis of Phenanthridinones from N-Methoxybenzamides and Aryltriethoxysilanes through RhIII-Catalyzed C−H and N−H Bond Activation. Chem. Asian J.2013, 8, 2175-2181.
  54. Chou, H. -H.; Li, Y. -K.; Chen, Y. -H.; Chang, C. -C.; Liao, C. -Y.; Cheng, C. -H.*New Iridium Dopants for White Phosphorescent Devices: Enhancement of Efficiency and Color Stability by an Energy Harvesting Layer. ACS Appl. Mater. Interfaces2013, 5, 6168-6175.
  55. Chen, C. -Y.; Tsai, H. -R.; Lu, K. -Y.; Yao, H. -H.; Ou-Yang, Y. -H.; Cheng, C. -H.*; Chen, I. -C.* Triscyclometalated Iridium(III) Fluoro-Substituted Carbene Complexes: Character of Emitting Triplet States and Excited State Dynamics. J. Chin. Chem. Soc.2013, 60, 965-973.
  56. Su, T. -H.; Fan, C. -H.; Ou-Yang, Y. -H.; Hsu, L. -C.; Cheng, C. -H.* Highly Efficient Deep-Red Organic Electrophosphorescence Devices with Excellent Operational Stability Using Bis(indoloquinoxalinyl) Derivatives as the Host Materials. J. Mater. Chem. C2013, 1, 5084-5092.
  57. Yang, C. -M.; Mannathan, S.; Cheng, C. -H.* Nickel-Catalyzed Chemo- and Stereoselective Alkenylative Cyclization of 1,6-Enynes with Alkenyl Boronic Acids. Chem. Eur. J.2013, 19, 12212-12216.
  58. Chang, C. -C.; Chen, C. -P.*; Chou, H. -H.*; Liao, C. -Y.; Chan, S. -H.; Cheng, C. -H.* New Selenophene-Based Low-Band Gap Conjugated Polymers for Organic Photovoltaics. J. Polym. Sci., Part A: Polym. Chem.2013, 51, 4550-4557.
  59. Huang, P. -C.;Gandeepan, P.; Cheng, C. -H.* Cu(I)-Catalyzed Intramolecular Oxidative C−H Amination of 2-Aminoacetophenones: a Convenient Route toward Isatins. Chem. Commun.2013, 49, 8540-8542.
  60. Luo, C. -Z.; Gandeepan, P.; Cheng, C. -H.* A Convenient Synthesis of Quinolizinium Salts through Rh(III) or Ru(II)-Catalyzed C−H Bond Activation of 2-Alkenylpyridine. Chem. Commun.2013,49, 8528-8530.
  61. Qi, H. -L.; Chen, Y. -H.; Cheng, C. -H.; Allen J. Bard*Electrochemistry and Electrogenerated Chemiluminescence of Three Phenanthrene Derivatives, Enhancement of Radical Stability, and Electrogenerated Chemiluminescence Efficiency by Substituent Groups. J. Am. Chem. Soc.2013,135, 9041-9049.
  62. Luo, C. -Z.; Gandeepan, P.; Jayakumar, J.; Parthasarathy, K.; Chang, Y. -W.; Cheng, C. -H.*Rh(III)-Catalyzed C−H Activation: A Versatile Route towards Various Polycyclic Pyridinium Salt. Chem. Eur. J.2013, 19, 14181-14186.
  63. Nasu, K.; Nakagawa, T.; Nomura, H.; Lin, C. -J.; Cheng, C. -H.; Tseng, M. -R.; Yasuda, T.; Adachi, C.* A Highly Luminescent Spiro-Anthracenone-BasedOrganic Light-Emitting Diode Exhibiting ThermallyActivated Delayed Fluorescence. Chem. Commun.2013, 49, 10385-10387.
  64. Chuang, S. -C.; Gandeepan, P.; Cheng, C. -H.* Synthesis of Isoquinolines via Rh(III)-Catalyzed C−H Activation Using Hydrazone as a New Oxidizing Directing Group. Org. Lett.2013, 15, 5750-5753.
  65. Lee, T. -H.; Jayakumar, J.; Cheng, C. -H.*; Chuang, S. -C.* One Pot Synthesis of Bioactive Benzopyranones Through Palladium-Catalyzed C−H Activation and CO Insertion into 2-Arylphenols. Chem. Commun.2013, 49, 11797-11799.
  66. Wu, T. -L.; Chou, H. -H.; Huang, P. -Y.; Cheng, C. -H.; Liu, R. -S.* 3,6,9,12-Tetrasubstituted Chrysenes: Synthesis, Photophysical Properties, and Application as Blue Fluorescent OLED. J. Org. Chem.2014, 79, 267-274.
  67. Mannathan, S.; Cheng, C. -H.* [4+2] vs [3+2] Annulations in the Nickel- and Cobalt-Catalyzed Reaction ofortho-Haloimines with Alkynes: Differential Reactivity towards the Synthesisof Isoquinolines and Aminoindenes. J. Chin. Chem. Soc.2014, 61, 59-66.
  68. Gandeepan, P.;Rajamalli, P.;Cheng, C. -H.* Synthesis of Substituted Quinolines by Iron(III)-Catalyzed Three-Component Coupling Reaction of Aldehydes, Amines, and Styrenes. Asian J. Org. Chem.2014, 3, 303-308.
  69. Senthilkumar, N.; Gandeepan, P.; Jayakumar, J.; Cheng, C. -H.* Rh(III)-Catalyzed Synthesis of 1-Substituted Isoquinolinium Salts via C−H Bond Activation Reaction of Ketimines with Alkynes. Chem. Commun.2014, 50, 3106-3108.
  70. Yeh, C. -H.; Lin, Y. -C.; Mannathan, S.; Hung, K.; Cheng, C. -H.* Ene-Carbonyl Reductive Coupling for the Synthesis of 3,3-Disubstituted Phthalide, 3-Hydroxyisoindolin-1-one and 3-Hydroxyoxindole Derivatives. Adv. Synth. Catal.2014,356, 831-842.
  71. Muralirajan, K.; Cheng, C. -H.* Regioselective Synthesis of Indoles via Rhodium-Catalyzed C−H Activation Directed by an In-Situ Generated Redox-Neutral Group. Adv. Synth. Catal.2014,356, 1571-1576.
  72. Mannathan, S.; Cheng, C. -H.* Nickel-Catalyzed Regio- and Stereoselective Reductive Coupling of Oxa- and Azabicyclic Alkenes with Enones and Electron-Rich Alkynes. Adv. Synth. Catal.2014,356, 2239-2246.
  73. Hong, Y. -C.; Gandeepan, P.; Mannathan, S.; Lee, W. -T.; Cheng, C. -H.* Alkene-Assisted Nickel-Catalyzed Regioselective 1,4-Addition of Organoboronic Acid to Dienones: A Direct Route to All-Carbon Quaternary Centers. Org. Lett.2014, 16, 2806-2809.
  74. Chen, C. -H.; Hsu, L. -C.; Rajamalli, P.; Chang, Y. -W.; Wu, F. -I.; Liao, C. -Y.; Chiu, M. -J.; Chou, P. -Y.; Huang, M. -J.; Chu, L. -K.; Cheng, C. -H.* Highly Efficient Orange and Deep-Red Organic Light Emitting Diodes with Long Operational Lifetimes using Carbazole-Quinoline Based Bipolar Host Materials. J. Mater. Chem. C 2014, 2, 6183-6191.
  75. Chou, P. -Y.; Chou, H. -H.; Chen, Y. -H.; Su, T. -H.; Liao, C. -Y.; Lin, H. -W.; Lin, W. -C.; Yen, H. -Y.; Chen, I. -C.; Cheng, C. -H.* Efficient Delayed Fluorescence viaTriplet-Triplet Annihilation for Deep-Blue Electroluminescence. Chem. Commun.2014, 50, 6869-6871.
  76. Jayakumar, J.; Kanniyappan P.; Lee, T. -H.; Chuang, S. -C.*; Cheng, C. -H.* One-Pot Synthesis of Highly Substituted Polyheteroaromatics by Rh(III)-Catalyzed Multiple C−H Activation and Annulation. Angew. Chem. 2014, 126, 10047-10050; Angew. Chem. Int. Ed.2014, 53, 9889-9892.
  77. Hung, C. -H.; Gandeepan, P.; Cheng, C. -H.* Ruthenium(II)-Catalyzed C−H Bond Activation: An Efficient Route toward Indenamines.ChemCatChem2014, 6, 2692-2697.
  78. Santhoshkumar, R.; Mannathan, S.;Cheng, C. -H.* Cobalt-Catalyzed Hydroarylative Cyclization of 1,6-Enynes with Aromatic Ketones and Esters via C−H Activation. Org. Lett.2014, 16, 4208-4211.
  79. Yeh, C. -H.; Chen, W. -C.; Gandeepan, P.; Hong, Y. -C.; Shih, C. -H.; Cheng, C. -H.* RhIII-Catalyzed Dual Directing Group Assisted Sterically Hindered C−H Bond Activation: a Unique Route to meta and orthoSubstituted Benzofurans. Org. Biomol. Chem.2014,12,9105-9108.
  80. Gandeepan, P.; Rajamalli, P.;Cheng, C. -H.* Palladium-Catalyzed Dehydrogenative β-Arylation of Simple Saturated Carbonyls by Aryl Halides. ACS Catal.2014,4,4485-4489.
  81. Shih, C. -H.; Rajamalli, P.; Wu, C. -A.; Chiu, M. -J.; Chu, L. -K.; Cheng, C. -H.* A High Triplet Energy, High Thermal Stability Oxadiazole Derivative as the Electron Transporter for Highly Efficient Red, Green and Blue Phosphorescent OLEDs. J. Mater. Chem. C2015, 3, 1491-1496.
  82. Gandeepan, P.; Cheng, C. -H.* Transition Metal Catalyzed π-Bond Assisted C−H Bond Functionalization: An Emerging Trend in Organic Synthesis.Chem. Asian J. 2015, 10, 824-838.
  83. Muralirajan, K.; Haridharan, R.; Prakash, S.; Cheng, C. -H.* Rhodium(III)-Catalyzed in situ Oxidizing Directing Group-Assisted C−H Bond Activation and Olefination: A Route to 2-Vinylanilines. Adv. Synth. Catal.2015, 357, 761-766.
  84. Haridharan, R.; Muralirajan, K.; Cheng, C. -H.* Rhodium(III)-Catalyzed ortho-Arylation of Anilides with Aryl Halides. Adv. Synth. Catal.2015, 357, 366-370.
  85. Luo, C. -Z.; Jayakumar, J.; Gandeepan, P.; Wu, Y. -C.; Cheng, C. -H.* Rhodium(III)-Catalyzed Vinylic C−H Activation: A Direct Route toward Pyridinium Salts. Org. Lett.2015, 17, 924-927.
  86. Rajamalli, P.; Gandeepan, P.; Huang, M. -J.; Cheng, C. -H.* Bromo Induced Reversible Distinct Color Switching of a Structurally Simple Donor-Acceptor Molecule by Vapo, Piezo and Thermal Stimuli. J. Mater. Chem. C 2015, 3, 3329-3335.
  87. Gandeepan, P.; Cheng, C. -H.* Cobalt Catalysis Involving π Components in Organic Synthesis. Acc. Chem. Res. 2015, 48, 1194-1206.
  88. Gandeepan, P.; Rajamalli, P.; Cheng, C. -H.* Rhodium(III)-Catalyzed [4+1] Annulation of Aromatic and Vinylic Carboxylic Acids with Allenes: An Efficient Method Towards Vinyl-Substituted Phthalides and 2-Furanones. Chem. Eur. J.2015, 21, 9198-9203.
  89. Shih, C. -H.; Rajamalli, P.; Wu, C. -A.; Hsieh, W. -T.; Cheng, C. -H.* A Universal Electron-Transporting/Exciton-Blocking Material for Blue, Green, and Red Phosphorescent Organic Light-Emitting Diodes (OLEDs). ACS Appl. Mater. Interfaces 2015, 7, 10466-10474.
  90. Liu, C. -C.; Hsieh, J. -C.; Korivi, R. P.; Cheng, C. -H.* Cobalt-Catalyzed Dual Annulation of o-Halobenzaldimine with Alkyne: A Powerful Route toward Bioactive Indenoisoquinolinones. Chem. Eur. J. 2015, 21, 9544-9549.
  91. Prakash, S.; Muralirajan, K.; Cheng, C. -H.* Rh-catalyzed oxidizing group-directed ortho C−H vinylation of arenes by vinylstannanes. Chem. Commun. 2015, 51, 13362-13364.
  92. Luo, C. -Z.; Gandeepan, P.; Wu, Y. -C.; Tsai, C. -H.; Cheng, C. -H.* Cooperative C(sp3)−H and C(sp2)−H Activation of 2-Ethylpyridines by Copper and Rhodium: A Route toward Quinolizinium Salts. ACS Catal. 2015, 5, 4837-4841.
  93. Lai, C. -C.; Huang, M. -J.; Chou, H. -H.; Liao, C. -Y.; Rajamalli, P.; Cheng, C. -H.* m-Indolocarbazole Derivative as a Universal Host Material for RGB and White Phosphorescent OLEDs. Adv. Funct. Mater. 2015, 25, 5548-5556.
  94. Luo, C. -Z.; Gandeepan, P.; Wu, Y. -C.; Chen, W. -C.; Cheng, C. -H.* Copper Promoted Synthesis of Substituted Quinolines from Benzylic Azides and Alkynes. RSC Adv. 2015, 5, 106012-106018.
  95. Santhoshkumar, R.; Mannathan, S.; Cheng, C. -H.* Ligand-Controlled Divergent C-H Functionalization of Aldehydes with Enynes by Cobalt Catalysts. J. Am. Chem. Soc. 2015, 137, 16116-16120.
  96. Prakash, S.; Muralirajan, K.; Cheng, C. -H.* Cobalt-Catalyzed Oxidative Annulation of Nitrogen-Containing Arenes with Alkynes: An Atom-Economical Route to Heterocyclic Quaternary Ammonium Salts. Angew. Chem.,2016, 128, 1876-1880; Angew. Chem. Int. Ed. 2016, 55, 1844-1848.
  97. Jayakumar, J.; Cheng, C. -H.* Direct Synthesis of Protoberberine Alkaloids by Rh-Catalyzed C−H Bond Activation as the Key Step. Chem. Eur. J. 2016, 22, 1800-1804.
  98. Gandeepan, P.; Cheng, C. -H.* Advancements in the Synthesis and Applications of Cationic N-Heterocycles through Transition Metal-Catalyzed C−H Activation. Chem. Asian J.2016, 11, 448-460.
  99. Rajamalli, P.; Senthilkumar, N.; Gandeepan, P.; Ren-Wu, C. -Z.; Lin, H. -W.; Cheng, C. -H.* A Thermally Activated Delayed Blue Fluorescent Emitter with Reversible Externally Tunable Emission. J. Mater. Chem. C 2016, 4, 900-904.
  100. Rajamalli, P.; Senthilkumar, N.; Gandeepan, P.; Huang, P. -Y.; Huang, M. -J.; Ren-Wu, C. -Z.; Yang, C. -Y.; Chiu, M. -J.; Chu, L. -K.; Lin, H. -W.; Cheng, C. -H.* A New Molecular Design Based on Thermally Activated Delayed Fluorescence for Highly Efficient Organic Light Emitting Diodes. J. Am. Chem. Soc. 2016, 138, 628-634.
  101. Gandeepan, P.; Rajamalli, P.; Cheng, C. -H.* Diastereoselective [3+2] Annulation of Aromatic/Vinylic Amides with Bicyclic Alkenes through Cobalt-Catalyzed C−H Activation and Intramolecular Nucleophilic Addition. Angew. Chem. 2016,128, 4380-4383; Angew. Chem. Int. Ed. 2016,55, 4308-4311.
  102. Muralirajan, K.; Kuppusamy, R.; Prakash, S.; Cheng, C. -H.* Easy Access to 1-Amino and 1-Carbon Substituted Isoquinolines via Cobalt-Catalyzed C−H/N−O Bond Activation. Adv. Synth. Catal. 2016, 358, 774-783.
  103. Santhoshkumar, R.; Hong, Y. -C.; Luo, C. -Z.; Wu, Y. -C.; Hung, C. -H.; Hwang, K. -Y.; Tu, A. -P.; Cheng, C. -H.* Synthesis of Vinyl Carboxylic Acids using Carbon Dioxide as a Carbon Source by Iron-Catalyzed Hydromagnesiation. ChemCatChem 2016,8, 2210-2213.
  104. Chen, Y. -H.; Lin, C. -C.; Huang, M. -J.*; Hung, K.; Wu, Y. -C.; Lin, W. -C.; Chen-Cheng, R. -W.; Lin, H. -W.; Cheng, C. -H.*, Superior Upconversion Fluorescence Dopants for Highly Efficient Deep-Blue Electroluminescent Devices. Chem. Sci. 2016,7, 4044-4051.
  105. Kuppusamy, R.; Muralirajan, K.; Cheng, C. -H.* Cobalt(III)-Catalyzed [5+1] Annulation for 2H-Chromenes Synthesis via Vinylic C−H Activation and Intramolecular Nucleophilic Addition.ACS Catal.2016, 6, 3909-3913.
  106. Chen, W. -C.; Gandeepan, P.; Tsai, C. -H.; Luo, C. -Z.; Rajamalli, P.; Cheng, C. -H.* A Concise Synthesis of Quinolinium, and Biquinolinium Salts and Biquinolines from Benzylic Azides and Alkenes Promoted by Copper(II) Species.RSC Adv. 2016, 6, 63390-63397.
  107. Boobalan, R.; Gandeepan, P.; Cheng, C. -H.* Ruthenium-Catalyzed C−H Alkynylation of Aromatic Amides with Hypervalent Iodine-Alkyne Reagents. Org. Lett. 2016, 18, 3314-3317.
  108. Upadhyay, N. S.; Jayakumar, J.; Cheng, C. -H.* Rhodium-Catalyzed Regioselective Synthesis of Isoindolium Salts from 2-Arylpyridines and Alkenes in Aqueous Medium under Oxygen. Adv. Synth. Catal. 2016, 358, 3381-3386.
  109. Rajamalli, P.; Senthilkumar, N.; Gandeepan, P.; Ren-Wu, C. -C.; Lin, H. -W.; Cheng, C. -H.*A Method for Reducing the Singlet-Triplet Energy Gaps of TADF Materials for Improving the Blue OLED Efficiency.ACS Appl. Mater. Interfaces 2016, 8, 27026-27034.
  110. Chang, Y. -W.; Huang, M. -J.; Lai, C. -C.; Chang, C. -C.; Huang, M. -P.; Liao, C. -Y.; Cheng, C. -H.*A Versatile Ferrocene-Containing Material as p-Type Charge Generation Layer for High-Performance Full Color Tandem OLEDs.Chem. Commun.2016, 52, 14294-14297.
  111. Boobalan, R.; Kuppusamy, R.; Santhoshkumar, R.; Gandeepan, P.; Cheng, C. -H.*Access to Isoquiniline-1(2H)-ones and Pyridones by Cobalt-Catalyzed Oxidative Annulation of Amides with Allenes. ChemCatChem 2017, 9, 273-277.
  112. Muralirajan, K.; Prakash, S.; Cheng, C. -H.*Cobalt-Catalyzed Mild Ring-Opening Addition of Arenes C−H Bond to 7-Oxabicyclic Alkenes.Adv. Synth. Catal.2017, 359, 513-518.
  113. Lin, C.-C.; Huang, M.-J.; Chiu, M.-J.; Huang, M.-P.; Chang, C.-C.; Liao, C.-Y.; Chiang, K.-M.; Shiau, Y.-J.; Chou, T.-Y.; Chu, L.-K.; Lin, H.-W.; Cheng, C.-H.*Molecular Design of Highly Efficient Thermally Activated Delayed Fluorescence Hosts for Blue Phosphorescent and Fluorescent Organic Light-Emitting Diodes.Chem. Mater. 2017, 29, 1527-1537.
  114. Upadhyay, N. S.; Jayakumar, J.; Cheng, C.-H.* Facile One-Pot Synthesis of 2,3-Dihydro-1H-indolizinium Derivatives by Rhodium(III)-Catalyzed Intramolecular Oxidative Annulation via C–H Activation: Application to Ficuseptine Synthesis. Chem. Commun. 2017, 53, 2491-2494.
  115. Rajamalli, P.; Thangaraji, V.; Senthilkumar, N.; Ren-Wu, C.-C.; Lin, H.-W.; Cheng, C.-H. * Thermally Activated Delayed Fluorescence Emitters with a m,m-Di-tert-butyl-carbazolyl Benzoylpyridine Core Achieving Extremely High Blue Electroluminescence Efficiencies. J. Mater. Chem. C 2017, 5, 2919-2926.
  116. Wu, T.-L.; Yeh, C.-H.; Hsiao, W.-T.; Huang, P.-Y.; Huang, M.-J.; Chiang, Y.-H.; Cheng, C.-H.*; Liu, R.-S.*; Chiu, P.-W.* High-Performance Organic Light Emitting Diode with Substitutionally Boron-doped Graphene Anode. ACS Appl. Mater. Interfaces 2017, 9, 14998-15004.
  117. Upadhyay, N. S.; Thorat, V. H.; Sato, R.; Annamalai, P.; Chuang, S.-C.; Cheng*, C.-H. Synthesis of Isoquinolones via Rh-Catalyzed C–H Activation of Substituted Benzamides Using Air as the Sole Oxidant in Water. Green Chem. 2017, 19, 3219-3224.
  118. Lee, W.-H.; Chen, C.-Y.; Li, C.-S.; Hsiao, S.-Y.; Tsai, W.-L.; Huang, M.-J.; Cheng, C.-H.; Wu, C.-I.*; Lin, H.-W.* Boosting Thin-Film Perovskite Solar Cell Efficiency through Vacuum-Deposited Sub-Nanometer Small-Molecule Electron Interfacial Layers. Nano Energy 2017, 38, 66-71.
  119. Rajamalli, P.; Senthilkumar, N.; Huang, P.-Y.; Ren-Wu, C.-C.; Lin, H.-W.; Cheng, C.-H.*New Molecular Design Concurrently Providing Superior Pure Blue, Thermally Activated Delayed Fluorescence and Optical Out-Coupling Efficiencies.J. Am. Chem. Soc.2017, 139, 10948-10951.
  120. Hung, C.-H.; Gandeepan, P.; Cheng, L.-C.; Chen, L.-Y.; Cheng, M.-J.; Cheng, C.-H.*Experimental and Theoretical Studies on Iron-Promoted Oxidative Annulation of Arylglyoxal with Alkyne: Unusual Addition and Migration on the Aryl Ring.J. Am. Chem. Soc. 2017, 139, 17015-17021.
  121. Hsieh, J.-C.*; Chu, Y.-H.; Muralirajan, K.; Cheng, C.-H.*A Simple Route to 1,4-Addition Reactions by Co-Catalyzed Reductive Coupling of Organic Tosylates and Triflates with Activated Alkenes.Chem. Commun. 2017, 53, 11584-11587.
  122. Chang, C. –C; Jiang, B. –H; Li, Y. –C; Chen, C. –P*; Cheng, C. –H.*Indacenodithiophene-based conjugated polymers incorporating alkylthiophene side chains: improvement of organic solar cell performance. Dyes and Pigments2017, 142, 139-146.
  123. Hsieh, J. –C*; Hong, Y. –C; Yang, C. –M; Mannathan, S.; Cheng, C. –H.* Nickel-catalyzed highly chemo-and stereoselective borylative cyclization of 1, 6-enynes with bis (pinacolato) diboron. Organic Chemistry Frontiers2017, 4 (8), 1615-1619.
  124. Jayakumar, J.; Cheng, C. -H.*Recent Advances in the Synthesis of Quaternary Ammonium Salts via Transition-Metal-Catalyzed C–H Bond Activation.J. Chin. Chem. Soc.2018, 65, 11-23.
  125. Thorat, V. H.; Upadhyay, N. S.; Murakami, M.*; Cheng, C. -H.*Nickel-Catalyzed Denitrogenative Annulation of 1,2,3-Benzotriazin-4-(3H)-ones with Benzynes for Construction of Phenanthridinone Scaffolds.Adv. Synth. Catal. 2018, 360, 284-289.
  126. Dai, S. -W.; Hsu, B. -W.; Chen, C. -Y.; Lee, C. -A.; Liu, H. -Y.; Wang, H. -F.; Huang, Y. -C.; Wu, T. -L.; Manikandan, A.; Ho, R. -M.; Tsao, C. -S.; Cheng, C. -H.; Chueh, Y. -L.; Lin, H. -W.*Perovskite Quantum Dots with Near Unity Solution and Neat-Film Photoluminescent Quantum Yield by Novel Spray Synthesis.Adv. Mater. 2018, DOI: 10.1002/adma.201705532.
  127. Prakash, S.; Kuppusamy, R.; Cheng, C. -H.*Cobalt-Catalyzed Annulation Reactions via C–H Bond Activation.ChemCatChem2018,10(4), 683-705.Minireview
  128. Wu, T. -L.; Huang, M. -J.; Lin, C. -C.; Huang, P. -Y.; Chen-Cheng, R. -W.; Lin, H. -W.*; Liu, R. -S.* Cheng, C. -H.* Diboron Compound-Based Organic Light-Emitting Diodes with High Efficiency and Reduced Efficiency Roll-Off Nat. Photonics2018, 12, 235-240.
  129. Kuppusamy, R.; Santhoshkumar, R.; Boobalan, R.; Wu, H. -R.; Cheng, C. -H.* Synthesis of 1,2-Dihydroquinolines by Co(III)-Catalyzed [3 + 3] Annulation of Anilides with Benzylallenes. ACS Catal.2018, 8, 1880-1883.
  130. Prakash, S.; Chang, Y. -C.; Cheng C. -H.*Rhenium(I)-Catalyzed ortho-C–H Addition to Bicyclic Alkenes. Chem. Asian J. 2018, 13, 1664-1668.
  131. Santhoshkumar, R.;Cheng C. -H.*Fickle Reactivity of Allenes in Transition‐Metal‐Catalyzed C−H Functionalizations. Asian J. Org. Chem. 2018, 7, 1151–1163.
  132. Santhoshkumar, R.;Cheng C. -H.*Hydroarylations by cobalt-catalyzed C–H activation. Beilstein J. Org. Chem. 2018, 14, 2266–2288.
  133. Jou, J. –H.*; Li, J. –L.; Sahoo, S.; Dubey, D. –K.; Yadav, R. A. K.; Joseph, V.; Thomas, K. R. J.; Cheng, C. –H. Enabling a 6.5% External Quantum Efficiency Deep-Blue Organic Light-Emitting Diode With a Solution-Processable Carbazole Based Emitter.J. Phys. Chem. C2018, 122 (42), 24295–24303.
  134. Chen, M. –H.; Hsieh, J. –C.*; Lee, Y. –H.; Cheng, C. –H. Controlled Synthesis of Enantioselective 1-Aminoindenes via Cobalt-Catalyzed [3+ 2] Annulation Reaction. ACS Catalysis 2018, 8 (10), 9364-9369.
  135. Dai,S. -W.; Hsu, B. –W.; Chen, C. –Y.; Lee, C. –A.; Liu, H. –Y.; Wang, H. –F.; Huang, Y. –C.; Wu, T. -L.; Manikandan, A.; Ho, R. –M.; Tsao, C. –S.; Cheng, C. –H.; Chueh, Y. –L.; Lin, H. –W.*Quantum Dots: Perovskite Quantum Dots with Near Unity Solution and Neat‐Film Photoluminescent Quantum Yield by Novel Spray Synthesis. Advanced Materials 2018, 30 (7), 1870048.
  136. Chang, Y. -C.; S Prakash, S.;Cheng, C. –H.* Re I-Catalyzed Highly Regio-and Stereoselective C‒H Addition to Terminal and Internal Alkynes. Organic Chemistry Frontiers, 2018.
  137. Wu, B. -H.; Huang, M. -J.; Lai, C. -C.; Cheng, C. -H.; Chen, I. -C.* Isomerization Reaction of mer- to fac-Tris(2-phenylpyridinato-N,C2’)Iridium(III) Monitored by Using Surface-Enhanced Raman Spectroscopy. Inorg. Chem.2018, 57, 4448-4455.
  138. Chiou, M. -F.; Jayakumar, J.; Cheng, C. -H.; Chuang, S. -C.* Impact of the Valence Charge of Transition Metals on the Cobalt- and Rhodium-Catalyzed Synthesis of Indenamines, Indenols, and Isoquinolinium Salts: A Catalytic Cycle Involving M(III)/M(V) [M = Co, Rh] for [4 + 2] Annulation. J. Org. Chem.2018, 83, 7814-7824.

 

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