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Cheng, Chien-Hong -2

Title: Professor & Vice President of Academic Affair

Education:

University of Rochester(USA)(Ph.D.) (1978)
National Tsing Hua University(M.S.) (1974)
National Tsing Hua University(B.S.) (1971)

Office: Chemistry Building R608
Phone number: 33381
E-mail: chcheng@mx.nthu.edu.tw
Web site: http://mx.nthu.edu.tw/~chcheng

Work Experience:

1984 ~
1979 ~ 1984
1978 ~ 1979

Professor of NTHU
Associate Professor of NTHU
Postdoctoral Research:University of Rochester

Research Areas:

(I). Transition metal-catalyzed carbon-carbon bond formation.
(II). Synthesis of new organic and organometallic electroluminescent materials and fabrication  
      of electroluminescent devices.


Journal Articles:

1.      Eisenberg, R.; Cheng, C. H. Catalyst System for Catalyzing the Water Gas Shift Reaction. U. S. Patent, 1976, 4, 107,076.
 
2.      Cheng, C. H.; Eisenberg, R. The Rhodium(I) Anion [Rh(CO)(PEt3)(maleonitriledithiolate)]-and Acyl Complexes Derived from its Reaction with Alkyl Halides. Inorg. Chem., 1977, 18, 148.
 
3.      Cheng, C. H.; Hendriksen, D. E.; Eisenberg, R. Homogeneous Catalysis of the Water Gas Shift Reaction Using Rhodium Carbonyl Iodide. J. Am. Chem. Soc., 1977, 99, 2791.
 
4.      Cheng, C. H.; Spivack, B. D.; Eisenberg, R. The Addition of Alkyl Halides to Rhodium(I) Dithiolene Complexes. The Synthesis, Structure, and Chemical Properties of Rhodium(III) Acyl Species. J. Am. Chem. Soc., 1977, 99, 3003.
 
5.      Cheng, C. H.; Hendriksen, D. E.; Eisenberg, R. A Reaction Rhodium(I) Carbonyl Dithiolate and the Formation of Acyl and Hydride Species. J. Organomet. Chem., 1977, 142, C65.
 
6.      Cheng, C. H.; Eisenberg, R. Homogeneous Catalysis of the Water Gas Shift Reaction Using Platinum-tin Complexes. J. Am. Chem. Soc., 1978, 100, 5968.
 
7.      Cheng, C. H.; Eisenberg, R. Alkyl Group Migration in Rhodium Carbonyl Dithiolates and the Molecular Structure of Carbonyl(triphenylphosphine) (1-(ethyl-thio) malenitrile-2-thiolate )rhodium, Rh(CO)(PPh3)(Etmnt). Inorg. Chem., 1979, 18, 2438.
 
8.      Cheng, C. H.; Kuritzkes, L.; Eisenberg, R. Olefin Hydrogention by Carbon Monoxide and Water Using a Platinum Chloride Tin Chloride Catalyst System. J. Organomet. Chem., 1980,19, C21.
 
9.      Sun, C. Y.; Fang, C. S.; Chang, S. D.; Cheng, C. H.; Yang, M. H.; Lin, H. H.; Mu, H. T. Growth and Process Identification of CuInS2 on GaP by Chemical Vapor Deposition. J. Crystal Growth, 1981, 55, 116.
 
10. Liou, K. F.; Cheng, C. H. Reduction of Aromatic Nitro Compounds by Secondary Alcohols Using Rhodium Complexes as Catalysts. J. Org. Chem., 1982, 47, 3018.
 
11. Chao, C. S.; Chang, C. T.; Cheng, C. H. New Method for the Preparation of Activated Nickel and Cobalt Powders and their Application in the Biaryl Synthesis. J. Org. Chem., 1983,48, 4904.
 
12. Chen, C. K.; Cheng, C. H. Interactions of Triangulo-m-carbonyldecacarbonyl-m-hydrotriferrate(1-), HFe3(CO)11-, with its Counter Cation and Solvent. Inorg. Chem., 1983,22, 3378.
 
13. Chung, T. F.; Wu, Y. M.; Cheng, C. H. Reduction of Aromatic Nitro Compounds by Ethylenediamine, a New Selective Reagent for the Synthesis of Symmetric Azo Species. J. Org. Chem., 1984, 49, 1215.
 
14. Ho, L. Y.; Wu, Y. M.; Cheng, C. H. Reaction of Nitrosobenzene with Aliphatic Amines. Pro. Nat1. Sci. Counc., Repub. China, Part B, 1984, 8, 93.
 
15. Wu, Y. M.; Ho, L. Y.; Cheng, C. H. (Phenylazo)alkanes from Reaction of Nitrosobenzene with Alkylamines. J. Org. Chem., 1985, 50, 392.
 
16. Fang, W. P.; Cheng, C. H. Homogeneous Catalytic Reduction of Nitric Oxide and Nitrous Oxide to Dinitrogen by Carbon Monoxide. J. Chem. Soc., Chem. Commun., 1986, 503.
 
17. Yang, S. H.; Lee, T.; Cheng, C. H. Reductive Coupling of Halomethylbenzene Derivatives by Nickel and Cobalt. J. Chin. Chem. Soc., 1986, 33, 193.
 
18. Yang, S. L.; Li, C. S.; Cheng, C. H. Electron Transfer Catalysis in the Conversion of Fe3(CO)12 to Fe(CO)5. J. Chem. Soc., Chem. Commun., 1987, 1872.
 
19. Yang, S. H.; Li, C. S.; Cheng, C. H. Halides Exchange Reactions Between Aryl Halides and Alkali Halides Catalyzed by Nickel Metal Powder. J. Org. Chem., 1987, 52, 691.
 
20. Chen, C. K.; Cheng, C. H. Ion Paring of [Fe3(m-H,m-CO)(CO)10]- with H2NR2+ CationsOrganometallics, 1987, 6, 868.
 
21. Yang, S. L.; Li, C. S.; Cheng, C. H. “Electron Transfer Catalysis in the Conversion of Fe3(CO)12 to Fe(CO)5” J. Chem. Soc., Chem. Commun. 1987, 1872.
 
22. Sun, K. S.; Cheng, C. H. Mechanism of Oxidation of CO by PtCl42-. An Investigation into the Nature of the Intermediates by Isotopic Labeling. J. Am. Chem. Soc., 1988, 110, 6744.
 
23. Sun, K. S.; Cheng, C. H. Catalytic Reduction of Nitric Oxide by Carbon Monoxide in the Presence of Platinum(II), Copper(I), and Copper(II). J. Chem. Soc., Chem. Commun., 1988, 209.
 
24. Lu, T. H.; Kao, H. Y.; Wu, D. I.; Kong, K. C.; Cheng, C. H. Structure of Bis-(2,2'-bipyridine) dicyanoiron(III) Perchlorate. Acta Cryst., 1988, C44, 1184.
 
25. Cheng, C. H. Reaction of Carbon Anions with Iron-Unsaturated Ketimine Complexes. J. Chin. Chem. Soc., 1988, 35, 261.
 
26. Chang, C. F.; Cheng, C. H.; Wang, C. C.; Wang, S. L. Structure of Bis(benzaldehydeazine) dichloropalladium(II). Acta Cryst., 1989, C45, 1705.
 
27. Li, C. S.; Cheng, C. H. Synthesis of Nortricyclene from Norbornadiene Using Palladium Complexes and Zinc Powder. J. Chem. Soc., Chem. Commun., 1990, 1774.
 
28. Cheng, C. H.; Lain, J. S.; Wu, Y. J.; Wang, S. L. Structure of Dichlorobis(3,5-dimethylpyrazole)palladium. Acta Cryst., 1990, C46, 208.
 
29. Semmelhack, M. F.; Cheng, C. H. A New Method for the Synthesis of Iron Azadiene and Diene Complexes. Reaction of (2-RCHCHCOR)Fe(CO)4 with Aniline and Ylide. J. Organoment. Chem., 1990, 393, 237.
 
30. Lain, J. S.; Cheng, C. H.; Cheng, C. Y.; Wang, S. L. Synthesis, Structure and Properties of Molybdenum(0) Bialkyne Complexes. J. Organomet. Chem., 1990, 390, 333.
 
31. Cheng, C. H.; Sun, K. S. Homogeneous Catalytic Reduction of Nitric Oxide by Olefin in the Presence of Palladium(II) Chloride. Inorg. Chem., 1990, 29, 2547.
 
32. Lee, J. D.; Fang, W. P.; Li, C. S.; Cheng, C. H. Catalytic Reduction of Nitrous Oxide by Carbon Monoxide in the Presence of Rhodium Carbonyl and Hydroxide. Evidences for an Electron-transfer and a Direct Oxygen-transfer Mechanism. J. Chem. Soc., Dalton Trans.,1991, 1923.
 
33. Sun, K. S.; Kong, K. C.; Cheng, C. H. Mechanistic Studies of the Catalytic Reduction of Nitric-Oxide by Carbon-Monoxide in the Presence of Platinum(II), Copper(I), and Copper(II).Inorg. Chem., 1991, 30, 1998.
 
34. Jou, D. C.; Cheng, C. H. A Modified Water-Gas shift Reaction - the Decomposition of Alkyl Formate in the Presence of Water Using a Ruthenium Carbonyl. J. Chin. Chem. Soc., 1991, 38, 235.
 
35. Kong, K. C.; Cheng, C. H. Facile Aryl Aryl Exchange Between the Palladium Center and Phosphine-Ligands in Palladium(II) Complexes. J. Am. Chem. Soc., 1991, 113, 6313.
 
36. Liu, C. H.; Cheng, C. H. The Role of Alcohol in the Catalytic Reductive Carbonylation of Nitrobenzenes to Carbamates in the Presence of Rh(CO)4- or Ru3(CO)12 J. Organomet. Chem.,1991, 420, 119.
 
37. Li, C. S.; Cheng, C. H.; Liao, F. L.; Wang, S. L. Insertion of Norbornadiene into the Aryl Palladium Bond - Synthesis Structure and Dynamics of Intramolecular h2-Arene Palladium Species. J. Chem. Soc.-Chem. Comm., 1991, 10, 710.
 
38. Luo, F. H.; Yang, S. L; Li, C. S.; Duan, J. P.; Cheng, C. H. Kinetics and EPR Spectral Evidence of an Electron-Transfer Chain Mechanism for PPh3 Substitution of Fe3(CO)12. J. Chem. Soc., Dalton Trans. 1991, 2435.
 
39. Duan, I.F ; Cheng, C. H.; Shaw, J. S.; Cheng, S. S.; Liou, K. F. Homo-Diels-Alder Cycloadditions Catalyzed by Cobalt Triphenylphosphine-Zinc Systems. J. Chem. Soc., Chem. Commun. 1991, 1347
 
40. Kong, K. C.; Cheng, C. H. Unsymmetric Biaryls from Dialkylacetylenes and Aryl Iodides in the Presence of Nickel Halide and Zinc Metal. J. Chem. Soc., Chem. Commun. 1991, 423.
 
41. Li, C. S.; Sun, K. S.; Cheng, C. H. Catalytic Reduction of Nitrous-Oxide to Dinitrogen by Carbon-Monoxide Using Group-8 Metal-Carbonyl Anions. J. Chem. Soc., Dalton Trans., 1992,6, 1025.
 
42. Kong, K. C.; Cheng, C. H. Synthesis of Spiro Dienones from Internal Acetylene and Cyclic 3-Iodo Enones in the Presence of Nickel Bromide and Zinc Powder. Organometallics, 1992, 11, 1972.
 
43. Lai, C. H.; Cheng, C. H.; Chou, W. C.; Wang, S. L.Synthesis, Structure, and Properties of Octahedral d6 bis(Alkene) Complexes of Molybdenum. Organometallics, 1993, 12, 1105.
 
44. Hsiao, T. Y.; Kuo, P. L.; Lai, C. H.; Cheng, C. H.; Cheng, C. Y.; Wang, S. L. Synthesis, Conformational Isomerism, and Fluxional Behavior of Octahedral bis(Alkyne)Tungsten(0) Complexes. Organometallics, 1993, 12, 1094.
 
45. Duan, J. P.; Cheng, C. H.Palladium-Catalyzed Stereoselective Reductive Coupling Reactions of Organic Halides with 7-Heteroatom Norbornadienes. Tetrahedron Lett., 1993, 34, 4019.
 
46. Lai, C. H.; Cheng, C. H.Mechanism of Alkene Rotation in Octahedral-D(6) trans-bis(Alkene) Complexes of Molybdenum. Organometallics, 1993, 12, 3561.
 
47. Li, C. S.; Jou, D. C.; Cheng, C. H.; Liao, F. L.; Wang, S. L. Addition of Organic Halides to Alkenes in the Presence of Palladium Complexes and Reducing Agents - 2,3-Dialkenylation of Norbornene and its Derivatives. Organometallics, 1993, 12, 3553.
 
48. Lai, C. H.; Cheng, C. H.; Chou, W. C.; Wang, S. L.Synthesis, Structure, and Isomerism of Octahedral bis(Maleate)Molybdenum(0) Complexes. Organometallics, 1993, 12, 3418.
 
49. Li, C. S.; Jou, D. C.; Cheng, C. H.Synthesis and Reactivities of Intramolecular eta(2)-Arene and eta(2)-Alkene Species via Insertion of Norbornadiene Into Palladium Carbon Bonds - Preparation of 3,5-Disubstituted Nortricyclenes from these Complexes. Organometallics, 1993,12, 3945.
 
50. Lai, C. H.; Cheng, C. H.; Cheng, C. Y.; Wang, S. L.Synthesis, Structure, and Properties of Molybdenum Octahedral D(6) bis(Alkyne) Complexes. J. Organomet. Chem., 1993, 458, 147.
 
51. Lai, C. H.; Cheng, C. H.; Liao, F. L.; Wang, S. L. Octahedral D(6) bis(Maleimide) and bis(Maleic Anhydride) Complexes of Molybdenum. Inorg. Chem., 1993, 32, 5658.
 
52. Lai, C. H.; Cheng, C. H. Mechanism of Alkene Rotation in Octahedral d6 Trans-bis(alkene) Complexes of Molybdenum. Organometallics 1993, 12, 3561-3564.
 
53. Lai, C. H.; Cheng, C. H.; Cheng, M. C.; Peng, S. M. Conformation of the Dimethyl Maleate ligands in a Molybdenum (0) Complex. Crystal Structure of d6 trans-Bis (dimethyl maleate)-dicarbonyl-o-phenylenediaminemolybdenum(0). J. Chin. Chem. Soc. 1993, 40, 445-450.
 
54. Liu, C. H.; Li, C. S.; Cheng, C. H.Ortho-Metalation of Intramolecular (eta(2)-Arene) Palladium Species and Reactivities of the Resulting Palladacycles. Organometallics, 1994, 13, 18.
 
55. Liu, C. H.; Cheng, C. H.; Cheng, M. C.; Peng, S. M.Palladium-Catalyzed Addition of Alkyne to Norbornene Derivatives-Unusual Ring Formation and Expasion Reactions. Organometallics,1994, 13, 1832.
 
56. Liu, T. W.; Chen, D. H.; Cheng, C. H.; Chang, C. T.; Sheen, S. R.; Huang, J. C.; Wu, M. K.Preparation and Properties of YBA2CU3OY-AG Composites via 8-Hydroxyquinoline Coprecipitation. Mater. Lett., 1994, 19, 301.
 
57. Wu, S. J.; Chen, D. H.; Liu, T. W.; Cheng, C. H.; Chang, C. T.; Sheen, S. R.; Wu, M. K.The Superconducting Properties and Crystal-Structure of YSR2 (CU0.9TI0.1)3O7+delta.Physica C., 1994, 226, 37.
 
58. Chen, D. H.; Liu, T. W.; Huang, J. C.; Cheng, C. H.; Chang, C. T.; Sheen, S. R.; Wang, T. C.; Wu, M. K.Synthesis of YBA2CU3O7 and YBA2CU4O8 Superconductors via Carbonate Coprecipitation. Mater. Lett., 1994, 21, 15.
 
59. Duan, J. P.; Cheng, C. H.Synthesis and Fluxional Behavior of Intramolecular eta(2)-Arene Complexes via Insertion of Substituted 7-Oxanorbornene into Palladium Carbon Bonds. J. Chin. Chem. Soc., 1994, 41, 749.
 
60. Chen, D. H.; Liu, L. T.; Cheng, C. H.; Wu, M. K.Variation of Hole Concentration and Structure Induced by Element Substitution at Y and CU Sites in the YSR2CU3O7-DELTA System. Physica C., 1994, C235, 555.
 
61. Huang, D. J.; Cheng, C. H. [2+2] Dimerization of Norbornadiene and its Derivatives in the Presence of Nickel-Complexes and Zinc Metal. J. Organomet. Chem., 1995, 490, C1.
 
62. Duan, J. P.; Cheng, C. H.Palladium-Catalyzed Reductive Couplings of Organic Halides with 7-Heteroatom Norbornadienes - New Synthetic Methods for Substituted Aryls and cis-1,2-Dihydro-1-Naphthyl Alcohols and Carbamates. Organometallics, 1995, 14, 1608.
 
 
63. Sheen, S. R.; Kao, C. H.; Wu, M. K.; Chen, D. H.; Huang, J. C.; Cheng, C. H.; Chang, C. T. Formation of YBA2CU4O8 Thick-Films via Spray-Pyrolysis. J. Chin. Chem. Soc., 1995, 42, 529.
 
64. Liao, H. Y.; Cheng, C. H.Synthesis of Isocoumarins from o-Iodobenzoic acid and Terminal Acetylenes Mediated by Palladium Complexes and Zinc-Chloride. J. Org. Chem., 1995, 60, 3711.
 
65. Liou, K. F.; Cheng, C. H.Cyclotrimerization of Alkynes with [60]Fullerene in the Presence of Tricyclohexylphosphine. J. Chem. Soc. Chem. Commun., 1995, 1603.
 
66. Liu, P. H.; Liao, H. Y.; Cheng, C. H.Electron - Transfer from Tetracarbonylrhodate(1-) to Nitro Aromatics - Novel Interaction of Nitro Radical-Anions with a Rhodium(I) Center. J. Chem. Soc. Chem. Commun., 1995, 2441.
 
67. Liou K. F.; Cheng, C. H.Phosphine-mediated [2+2] cycloaddition of internal alk-2-ynoate and alk-2-ynone to [60] fullerene. J. Chem. Soc., Chem. Commun., 1995, 2473.
 
68. Huang, J. C.; Cheng, C. H.; Sheen, S. R.; Leeb, Z. L.; Lei, C. M.; Wu, M. K. Preparation of Y2Ba4Cu7O15-delta superconductor without high oxygen pressure. J. Chin. Chem. Soc.,1996, 43, 139.
 
69. Liou, K. F.; Cheng, C. H. Photoinduced reactions of tertiary amines with [60]fullerene; Addition of an alpha-C-H bond of amines to [60]fullerene. Chem. Commun., 1996, 1423.
 
70. Duan, J. P.; Liao, F. L.; Wang, S. L.; Cheng, C. H. Synthesis of eta (2) – phosphonioalkene – palladium(O) complexes from alkenylphosphonium halides and palladium(O) species. Structure and substitution reactions of these complexes. Organometallics, 1997, 16, 3934.
 
71. Jou, D. C. ; Hsiao, T. Y. ; Wu, M. Y. ; Kong, K. C. ; Cheng, C. H.Nickel-catalyzed regio- and stereoselective homo 1,4-dialkenylation of conjugated dienes. Tetrahedron, 1998, 54, 1041.
 
72. Huang, C. C.; Duan, J. P.; Wu, M. Y.; Liao, F. L.; Wang, S. L.; Cheng, C. H. Synthesis and structure of eta(2)-phosphonioalkene-palladium(0) complexes. A catalyst intermediate in the palladium-mediated synthesis of alkenylphosphonium halides. Organometallics, 1998, 17, 676.
 
73. Luo, F. H.; Chu, C. I.; Cheng, C. H. Nitrile-group transfer from solvents to aryl halides. Novel carbon-carbon bond formation and cleavage mediated by palladium and zinc species.Organometallics, 1998, 17, 1025.
 
74. Liou, K. F.; Hsiao, T. Y.; Cheng, C. H. Diels-Alder reaction of [60]fullerene with dienes having an ester substituent at 1-position. Fullerene Sci. Technol., 1998, 6, 351.
 
75. Hsiao, T. Y.; Chidambareswaran, S. K.; Cheng, C. H. Novel bismethanofullerenes and ethenofullerene from the reaction of propiolates with C-60 in the presence of triphenylphosphine. J. Org. Chem., 1998, 63, 8617.
 
76. Hsiao, T.Y.; Santhosh, K.C.; Liou, K. F.; Cheng, C. H. Nickel-promoted first ene-diyne cycloaddition reaction on C-60: Synthesis and photochemistry of the fullerene derivatives. J. Am. Chem. Soc., 1998, 120, 12232.
 
77. Huang, D. J.; Sambaiah, T.; Cheng, C. H. Nickel-catalyzed cocyclotrimerization of oxa- and azabenzonorbornadienes with alkynes: reaction with multiple synthetic applications. New J. Chem., 1998, 22, 1147.
 
78. Wang, I. C.; Tai, L. A.; Lee, D. D.; Kanakamma, P. P.; Shen, C. K.-F.; Luh, T. Y.; Cheng, C. H.; Hwang, K. C. C60 and Water-Soluble Fullerene Derivatives as Antioxidants Against Radical-Initiated Lipid Peroxidation. J. Med. Chem., 1999, 42, 4614.
 
79. Chuang, S. C.; Lee, D. D.; Santhosh, K. C.; Cheng, C. H. Fullerene Derivatives Bearing a Phosphite Ylide, Phosphonate, Phosphine Oxide and Phosphonic Acid: Synthesis and Reactivities. J. Org. Chem., 1999, 64, 8868.
 
80. Yang, F. Y.; Wu, M. Y.; Cheng, C. H. Carbostannylation of Allenes Catalyzed by a Palladium Complex. Tetrahedron Lett., 1999, 40, 6055.
 
81. Sambaiah, T.; Cheng C. H. Nickel-Catalyzed Cocyclotrimerization and Cocyclodimerization of Alkenes and Alkynes. Bull. Inst. Chem., Academia Sinica,. 1999, 46, 41.
 
82. Chuang, S. C.; Santhosh, K. C.; Lin, C. H.; Wang, S. L.; Cheng, C. H. Synthesis and Chemistry of Fullerene Derivatives Bearing Phosphorus Substituents. Unusual Reaction of Phosphines with Electron-Deficient Acetylenes and C60. J. Org. Chem., 1999, 64, 6664.
 
83. Lin, H. L.; Yu, T. L.; Cheng, C. H. Dynamic Light Scattering from Sol-Gel Transition of Unsaturated Polyester Resins. Macromolecules, 1999, 32, 690.
 
84. Sambaiah, T.; Li, L. P.; Huang, D. J.; Lin, C. H.; Rayabarapu, D. K.; Cheng. C. H. Highly Regio- and Stereoselective Cocyclotrimerization and Linear Cotrimerization of a,b-Unsaturated Carbonyl Compounds with Alkynes Catalyzed by Nickel Complexes. J. Org. Chem., 1999, 64, 3663.
 
85. Feng, C. C.; Nandi, M.; Sambaiah, T.; Cheng, C. H. Nickel-Catalyzed Highly Stereoselective Ring Opening of 7-Oxa- and Azanorbornenes with Electrophilic Organic Halides.J. Org. Chem., 1999, 64, 3538.
 
86. Wu, M. Y.; Yang, F. Y.; Cheng, C. H. Carbosilylation of Allenes Catalyzed by Palladium Complexes: A New Efficient Route to substituted Allylic Silanes. J. Org. Chem., 1999, 64, 2471.
 
87. Sambaiah, T.; Huang, D. J.; Cheng, C. H. Stereoselective [2+2+2] Cocyclotrimerization of Oxa- and Azabenzonorbornadienes with Alkynes Catalyzed by Nickel Complexes: First Transition Metal-Mediated Synthesis of Isobenzofuran and Isoindole Precursors. J. Chem. Soc. Perkin Trans 1, 2000, 2, 195.
 
88. Chang, H. M.; Cheng, C. H. Palladium-Catalyzed Synthesis of 1,3-Dienes from Allenes and Organic Halides. J. Org. Chem., 2000, 65, 1767.
 
89. Lin, H. L.; Yu, T. L.; Cheng, C. H. Reentrant Behavior of Poly(vinyl alcohol)-Borax Semidilute Aqueous Solutions. Colloid & Polymer Science, 2000, 278, 187.
 
90. Huang, D. J.; Li, L. P.; Rayabarapu, D. K.; Sambaiah, T.; Cheng, C. H. Nickel-Catalyzed [2+2] Cycloaddition of Alkynes with Activated Cyclic Alkenes: Synthesis and Novel Ring Expansion Studies of Cyclobutene Products. Chem. Eur. J., 2000, 6, 3706.
 
91. Yang, F, Y.; Wu, M. Y.; Cheng, C. H. Highly Regio- and Stereoselective Acylboration of Allenes Catalyzed by Palladium Complexes: An Efficient Route to a New Class of 2-Acylallylboronates. J. Am. Chem. Soc., 2000, 122, 7122.
 
92. Chang, H. M.; Cheng, C. H. Palladium-Catalyzed Carboazidation of Allenes with Aryl Iodides and Trimethylsilyl Azide. J. Chem. Soc. Perkin Trans. 1, 2000, 22, 3799.
 
93. Majumdar, K. K.; Cheng, C. H. Ni(II)/Zn Mediated Chemoselective Arylation of Aromatic Aldehydes: Facile Synthesis of Diaryl Carbinols. Org. Lett., 2000, 2, 2295.
 
94. Chang, H. M; Cheng, C. H. Highly Regioselective and Stereoselective Allylation of Aldehydes via Palladium- Catalyzed In Situ Hydrostannylation of Allenes. Org. Lett., 2000, 2, 3439.
 
95. Chuang, S. C.; Shih, H. T.; Cheng, C. H. Interaction of Magnesium and Lithium Ions with [60] Fullerene Derivatives Bearing a Phosphorus Ylide Group. Full. Sci. Tec.2001, 9, 233.,
 
96. Rayabarapu, D. K.; Sambaiah, T.; Cheng, C. H. Nickel-Catalyzed Highly Regio- and Stereoselective Cyclization of Bicyclic Alkenes with Alkyl Propiolates: A Novel Method for the Synthesis of Benzocoumarin Derivatives. Angew. Chem., 2001, 40, 1286.
 
97. Yang, F, Y.; Cheng, C. H. Unusual Diboration of Allenes Catalyzed by Palladium Complexes and Organic Iodides: A New Efficient Route to Biboronic Compounds. J. Am. Chem. Soc., 2001,123, 761.
 
98. Shih, H. T., Shih, H. H.; Cheng, C. H. Synthesis of Biaryls via Unusual Deoxygenative Dimerization of 1,4-Epoxy-1,4-dihydroarenes Catalyzed by Palladium Complexes. Org. Lett.,2001, 3, 811.
 
99. Rayabarapu, D. K.; Majumdar, K. K.; Sambaiah, T.; Cheng C. H. Unusual Regioselective 1,4-Addition of 2-Pyridyl Carboxylate to Benzyne: A Facile Entry into 1-(2-Acylphenyl)-2-pyridones. J. Org. Chem., 2001, 66, 3646.
 
100. Chao, K. C.; Rayabarapu, D. K.; Wang, C. C.; Cheng, C. H. Cross [2+2] Cycloaddition of Bicyclic Alkenes with Alkynes Mediated by Cobalt Complexes: A Facile Synthesis of Cyclobutene Derivatives. J. Org. Chem., 2001, 66, 8804.
 
101. Shanmugasundaram, M.; Wu, M. S.; Cheng, C. H. Nickel-Catalyzed Highly Regio- and Chemoselective Cocyclotrimerization of Propiolates with Allenes: A Novel Route to Polysubstituted Benzene Derivatives. Org. Lett., 2001, 3, 4233.
 
102. Rayabarapu, D. K.; Cheng, C. H. Novel Cyclization and Reductive Coupling of Bicyclic Olefins with Alkyl Propiolates Catalyzed by Nickel Complexes. Pure. Appl. Chem., 2002, 74,69.
 
103. Jeevanandam, A.; Korivi, R. P.; Huang, I. W.; Cheng, C. H. Ni-Catalyzed Highly Regio- and Chemoselective Cocycloaddition of Nonconjugated Diynes with 1,3-Diynes: A Novel Method for Polysubstituted Arylalkynes. Org. Lett., 2002, 4, 807.
 
104. Huang, Y. C.; Majumdar, K. K.; Cheng, C. H. Nickel-Catalyzed Coupling of Aryl Iodides with Aromatic Aldehydes: Biaryl Ketone Synthesis and Mechanistic Investigations. J. Org. Chem.,2002, 67, 1682.
 
105. Huang, T. H.; Chang, H. M.; Wu, M. Y.; Cheng, C. H. Palladium-Catalyzed Three-Component Assembling of Allenes, Organic Halides, and Arylboronic Acids. J. Org. Chem.,2002, 67, 99.
 
106. Rayabarapu, D. K.; Chiou, C. F.; Cheng, C. H. Highly Stereoselective Ring-Opening Addition of Terminal Acetylenes to Bicyclic Olefins Catalyzed by Nickel Complexes. Org. Lett.,2002, 4, 1679.
 
107. Rayabarapu, D. K.; Cheng, C. H. Nickel-Catalyzed Regioselective Carbocyclization ofortho-Halophenyl Ketones with Propiolates: An Efficient Route to Disubstituted Indenols. Chem. Commun., 2002, 942.
 
108. Rayabarapu, D. K.; Cheng, C. H. Synthesis of Seven-Membered Lactones via Nickel and Zinc-Catalyzed Highly Regio- and Stereoselective Cyclization of 2-Iodobenzyl Alcohols with Propiolates. J. Am. Chem. Soc.,2002, 124, 5630.
 
109. Sun, P. P.; Duan, J. P.; Shih, H. T.; Cheng, C. H. Europium Complex as a Highly Efficient Red Emitter in Electroluminescent Devices, Appl. Phys. Lett., 2002, 81, 792.
 
110. Shih, H. T.; Lin, C. H.; Shih, H. H.; Cheng, C. H. High-Performance Blue Electroluminecent Devices Based on a Biaryl. Adv. Mater., 2002, 14, 1409.
 
111. Shanmugasundaram, M.; Wu, M. S.; Jeganmohan, M.; Huang, C. W.; Cheng, C. H. Highly Regio- and Chemoselective [2+2+2] Cycloaddition of Electron-Deficient Diynes with Allenes Catalyzed by Nickel Complexes: A Novel Entry to Polysubstituted Benzene Derivatives. J. Org. Chem., 2002, 67, 7724.
 
112. Jeganmohan, M.; Shanmugasundaram, M.; Huang, C. W.; Chang, K. J.; Cheng, C. H. Highly Regio- and Stereoselective Silystannation of Allenes Catalyzed by Phosphine-Free Palladium Complexes. Chem. Comm., 2002, 2552.
 
113. Yu, M. X.; Duan, J. P.; Lin, C. H.; Cheng, C. H.; Tao, Y. T. Diaminoanthracene Derivative as a High-Performance Green Host Electroluminescent Material. Chem. Mater., 2002, 14, 3958.
 
114. Wang, C. C.; Lin, P. S.; Cheng, C. H. Cobalt-Catalyzed Highly Regio- and Stereoselective Intermolecular Ene-Yne Reductive Coupling of Alkynes with Conjugated Alkenes. J. Am. Chem. Soc.,2002, 124, 9696.
 
115. Lin, H. L.; Liu, W. H.; Liu, Y. F.; Cheng, C. H. Complexation Equilibrium Constants of Poly(vinyl alcohol)-Borax Dilute Aqueous Solu
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