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Liaw, Wen-Feng -2

Title： Professor

Education：

Texas A&M University(USA)(Ph.D.) (1989)
National Tsing Hua University(B.S.) (1981)
Office： Chemistry Building R726
Phone number： 35663     Fax number：+886-3-5711082
E-mail： wfliaw@mx.nthu.edu.tw
Web site： http://my.nthu.edu.tw/~chem/faculty/e-wfliaw_web/e-wfliawweb.html

Work Experience：

2002 ~
1994 ~ 2002
1991 ~ 1994
Professor of NTHU
Professor of NCUE
Associate Professor of NCUE

Research Areas：

Inorganic Chemistry、Biochemistry


Journal Articles：
  1. Fu-Te Tsai, Ting-Shen Kuo, Wen-Feng Liaw*  “Reversible Transformation between the Six-Coordinate {Fe(NO)2}9 [(η2-ONO)(1-MeIm)2Fe(NO)2] (g = 2.013) and Four-Coordinate {Fe(NO)2}9 [(ONO)(1-MeIm)Fe(NO)2] (g = 2.03)” Submitted to J. Am. Chem. Soc. 2009, 131,
     
  2. Hsiao-Wen Huang,Chih-Chin Tsou,Ting-Shen Kuo,Wen-Feng Liaw*  “New Members of a Class of Dinitrosyl Iron Complexes (DNICs): Interconversion and Spectroscopic Discrimination of the Anionic {Fe(NO)2}9 [(NO)2Fe(C3H3N2)2]– and [(NO)2Fe(C3H3N2)(SR)]– (C3H3N2 = Deprotonated Imidazole ; R = tBu, Et, Ph)” Inorg. Chem. 2008, 47, 2196-2204.
     
  3. Tsai-Te Lu, Chih-Chin Tsou, Hsiao-Wen Huang,I-Jui Hsu, Jin-Ming Chen, Ting-Shen Kuo,Yu Wang,*Wen-Feng Liaw* “Anionic Roussin’s Red Esters (RREs) syn-/anti-Tzung-Wen Chiou, Wen-Feng Liaw* “”Inorg. Chem. 2008, 47, 7909-7913.
     
  4. Tzung-Wen Chiou, Wen-Feng Liaw* “Nickel-Thiolate and Iron-Thiolate Cyanocarbonyl Complexes: Modeling the Nickel and Iron Sites of [NiFe] Hydrogenase” C. R.. Chimie 2008, 11, 818-833.  (Invited Review).
     
  5.  Feng-Chun Lo, Chang-Li Chen, Chien-Ming Lee, Ming-Che Tsai, Tsai-Te Lu, Wen-Feng Liaw, Steve S.-F. Yu* “A study of NO trafficking from dinitrosyl-iron complexes to the recombinant E. coli transcriptional factor SoxR” J. Biol. Inorg. Chem. 2008, 13, 961-972.
     
  6. Yi-Ju Chen, Wei-Chi Ku, Li-Ting Feng, Ming-Li Tsai, Chung-Hung Hsieh, Wen-Hwei Hsu, Wen-Feng Liaw, Chen-Hsiung Hung,* Yu-Ju Chen* “Nitric oxide physiological responses and delivery mechanisms probed by water-soluble Roussin’s Red Ester and {Fe(NO)2}10 DNIC” J. Am. Chem. Soc. 2008, 130, 10929-10938.
     
  7. Chia-Huei Lin,Chien-Ge Chen,Ming-Li Tsai,Gene-Hsiang Lee, Wen-Feng Liaw*“Monoanionic {Mn(NO)}5 and Dianionic {Mn(NO)}6 Thiolato Nitrosyl Manganese Complexes: [(NO)Mn(L)2]–and [(NO)Mn(L)2]2– (LH2 = 1,2-Benzenedithiol and Toluene-3,4-Dithiol)” Inorg. Chem. 2008,47, 11435-11443.
     
  8. Chih-Chin Tsou, Zong-Sian Lin, Tsai-Te Lu,Wen-Feng Liaw* “Transformation of Dinitrosyl Iron Complexes (DNICs) [(NO)2Fe(SR)2]– (R = Et, Ph) into [4Fe-4S] Clusters [Fe4S4(SR)4]2–: Relevance to the Repair of the Nitric Oxide-Modified Ferredoxin [4Fe-4S] Clusters” J. Am. Chem. Soc. 2008, 130, 17154-17160.
     
  9. Tsai ML, Hsieh CH, Liaw WF “Dinitrosyl iron complexes (DNICs) containing S/N/O ligation: Transformation of Roussin's red ester into the neutral {Fe(NO)(2)}(10) DNICs” Inorg. Chem.,2007, 46 (12): 5110-5117.
     
  10. Hsu IJ, Hsieh CH, Ke SC, Liaw WF , et al. “New members of a class of iron-thiolate-nitrosyl compounds: Trinuclear iron-thiolate-nitrosyl complexes containing Fe3S6 core” J. Am. Chem. Soc. 2007, 129 (5): 1151-1159 
     
  11. Chih-Chin Tsou, Tsai-Te Lu, Wen-Feng Liaw* “EPR, UV-vis, IR and X-ray Demonstration of the Anionic Dimeric Dinitrosyl Iron Complex [(NO)2Fe(µ-StBu)2Fe(NO)2]–: Relevance to the Products of Nitrosylation of Cytosolic and Mitochondrial Aconitases, and High-Potential Iron Proteins” J. Am. Chem. Soc. 2007, 129, 12626-12627.
     
  12. Chien-Ming Lee, Tzung-Wen Chiou, Hsin-Hung Chen, Chao-Yi Chiang, Ting-Shen Kuo,‡ Wen-Feng Liaw* “Mononuclear Ni(II)-Thiolate Complexes with Pendant Thiol and Dinuclear Ni(III/II)-Thiolate Complexes with Ni…Ni Interaction Regulated by the Oxidation Levels of Nickels and the Coordinated Ligands” Inorg. Chem. 2007, 46, 8913-8923.
     
  13. Chien-Hong Chen, Gene-Hsiang Lee, Wen-Feng Liaw* “Mononuclear [NiII(L)(P-(o-C6H4S)2(o-C6H4SH))]0/1– (L = Thiolate, Selenolate, PPh3, and Cl) Complexes with Intramolecular [Ni－S…H－S]/[Ni…H－S] Interactions Modulated by the Coordinated Ligand L: Relevance to the [NiFe] Hydrogenases” Inorg. Chem. 2006, 45, 2307-2316.
     
  14. Tai-Nan Chen, Feng-Chun Lo, Ming-Li Tsai, Ko-Nien Shih,* Ming-Hsi Chiang, Gene-Hsiang Lee, Wen-Feng Liaw* “Dinitrosyl iron complexes [E5Fe(NO)2]– (E = S, Se): a precursor of Roussin’s black salt [Fe4E3(NO)7]–” Inorg. Chimi. Acta 2006, 359, 2525-2533.
     
  15. Mu-Cheng Hung, Ming-Che Tsai, Gene-Hsiang Lee, Wen-Feng Liaw* “Transformation and Structural Discrimination between the Neutral {Fe(NO)2}10 Dinitrosyl Iron Complexes (DNICs) and the Anionic/Cationic {Fe(NO)2}9 DNICs ” Inorg. Chem. 2006, 45, 6041-6047.
     
  16. Ming-Li Tsai, Wen-Feng Liaw* “Neutral {Fe(NO)2}9 Dinitosyl Iron Complex (DNIC) [(SC6H4-o-NHCOPh)(Im)Fe(NO)2] (Im = imidazole): Interconversion among the Anionic/Neutral {Fe(NO)2}9 DNICs and Roussin’s Red Ester ” Inorg. Chem. 2006, 45, 6583-6585.
     
  17. Tsai-Te Lu, Show-Jen Chiou, Chun-Yu Chen, Wen-Feng Liaw* “Mononitrosyl Tris(Thiolate) Iron Complex [Fe(NO)(SPh)3]– and Dinitrosyl Iron Complex [(EtS)2Fe(NO)2]–: Formation Pathway of Dinitrosyl Iron Complexes (DNICs) from Nitrosyltion of Biomimetic Rubredoxin [Fe(SR)4]2–/1– (R = Ph, Et)” Inorg. Chem. 2006, 45, 8799-8806.
     
  18. Chien-Ming Lee, Ya-Lan Chuang, Chao-Yi Chiang, Gene-Hsiang Lee, Wen-Feng Liaw* “Mononuclear Ni(III) Complexes [NiIII(L)(P(C6H3-3-SiMe3-2-S)3)]0/1– (L = Thiolate, Selenolate, CH2CN, Cl, PPh3): Relevance to the Nickel Site of [NiFe] Hydrogenases“ Inorg. Chem. 2006, 45, 10895-10904.
     
  19. Hao-Wen Chen, Chin-Wei Lin, Chiao-Chun Chen, Li-Bo Yang, Ming-Hsi Chiang, Wen-Feng Liaw* “Homodinuclear Iron-Thiolate Nitrosyl Compounds [(ON)Fe(S,S-C6H4)2Fe(NO)2]— and [(ON)Fe(SO2,S-C6H4)(S,S-C6H4)Fe(NO)2]— with {Fe(NO)}7-{Fe(NO)2}9 Electronic Coupling: New Members of A Class of Dinitrosyl Iron Complexes” Inorg. Chem. 2005, 44, 3226-3232.
     
  20. Fu-Te Tsai, Show-Jen Chiou, Ming-Che Tsai, Ming-Li Tsai, Hsiao-Wen Huang, Ming-Hsi Chiang, Wen-Feng Liaw* “Dinitrosyl Iron Complexes (DNICs) [L2Fe(NO)2]– (L = Thiolate): Interconversion among {Fe(NO)2}9 DNICs, {Fe(NO)2}10 DNICs and [2Fe-2S] Clusters, and the Critical Role of the Thiolate Ligands in Regulating NO Release of DNICs” Inorg. Chem. 2005, 44, 5872-5881.
     
  21. Chien-Ming Lee, Chien-Hong Chen, Hao-Wen Chen, Jo-Lu Hsu, Gene-Hsiang Lee, Wen-Feng Liaw* “Nitrosylated Iron-Thiolate-Sulfinate Complexes with {Fe(NO)}6/7 Electronic Cores: Relevance to the Transformation between the Active and Inactive NO-Bound Forms of Fe-Containing Nitrile Hydratases” Inorg. Chem. 2005, 44, 6670-6679.
     
  22. Wen-Feng Liaw, “Nickel: Models of Protein Active Sites” In Encyclopedia of Inorganic Chemistry, Second Edition., Robert A. Scott, Eds.; John Wiley & Sons: 2005.
     
  23. Chien-Ming Lee, Chien-Hong Chen, Shyue-Chu Ke, Gene-Hsiang Lee, Wen-Feng Liaw* “Mononuclear Nickel(III) and Nickel(II) Thiolate Complexes with Intramolecular S-H Proton Interacting with Both Sulfur and Nickel: Relevance to the [NiFe]/[NiFeSe] Hydrogeanses” J. Am. Chem. Soc. 2004, 126, 8406-8412.
     
  24. Ming-Li Tsai, Chiao-Chun Chen, I-Jui Hsu, Shyue-Chu Ke, Chung-Hung Hsieh, Kuo-An Chiang, Gene-Hsiang Lee, Yu Wang, Wen-Feng Liaw* “Photochemistry of the Dinitrosyl Iron Complex [S5Fe(NO)2]- Leading to Reversible Formation of [S5Fe(µ-S)2FeS5]2-: Spectroscopic Characterization of Species Relevant to the Nitric Oxide Modification and Repair of [2Fe-2S] Ferredoxins” Inorg. Chem. 2004, 43, 5159-5167.
     
  25. Chien-Hong Chen, Yung-Su Chang, Chien-Yeh Yang, Tai-Nan Chen, Chien-Ming Lee, Wen-Feng Liaw “Preparative and Structural Studies on Iron(II)-Thiolate Cyanocarbonyls: Relevance to the [NiFe]/[Fe]-Hydrogenases” Dalton Trans. 2004, 137-143.
     
  26. Chung-Hung Hsieh, I-Jui Hsu, Chien-Ming Lee, Shyue-Chu Ke, Tze-Yuan Wang, Gene-Hsiang Lee, Yu Wang, Jin-Ming Chen, Jyh-Fu Lee, Wen-Feng Liaw “Nickel Complexes of o-amidochalcogenophenolate(2-) /o-iminochalcogenobenzosemiquinonate(1-) -radical: Synthesis, Structures, Electron Spin Resonance and X-ray Absorption Spectroscopic Evidence”Inorg. Chem. 2003, 42, 3925-3933.
     
  27. Chien-Ming Lee, Chung-Hung Hsieh, Amitava Dutta, Gene-Hsiang Lee, Wen-Feng Liaw “Reversible Oxygen Binding to Sulfur in Nitrosylated Iron-Thiolate Complexes: Relevance to the Fe-Containing Nitrile Hydratases” J. Am. Chem. Soc. 2003, 125, 11492-11493.
     
  28. Wen-Feng Liaw,*Wen-Ting Tsai,Hung-Bin Gau,Chien-Ming Lee,Shin-Yuan Chou,Wen-Yuan Chen,Gene-Hsiang Lee“Dinuclear Iron(II)-Cyanocarbonyl Complexes Linked by Two/Three Bridging Ethylthiolates: Relevance to the Active-Site of [Fe] Hydrogenases” Inorg. Chem.2003, 42, 2783-2788.

 

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